Русская версия English version

Water-chemical regime with use of VTIAMIN reagents at TTP with seasonal mode of operation

A.A. Zidikhanova, A.B. Larin

Vestnik IGEU, 2024 issue 2, pp. 5—14

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Abstract in English: 

Background. The main equipment of the thermal power plant (TPP) includes a E-120-7.0-500GM steam boiler produced by LLC “Belenergomash – BZEM” with a single-stage evaporation circuit. The operating mode of the thermal power plant has seasonal characteristics. During the period of February to the end of August the equipment is stopped as a reserve. Dosing of AMINAT PK-3 does not provide the required pH level in steam and feed water, so the reagent for water-chemical regime and preservation has been substituted with VTIAMIN KR-33. The complex reagent VTIAMIN KR-33 ensures both the maintenance of the required quality indicators of the coolant along the path and promotes the formation of a protective barrier film on the internal heating surfaces.

Materials and methods. To check water-chemical regime, the existing automatic chemical control system has been updated. Panels have been installed for automatic chemical control of pH value, electrical conductivity of direct and H-cationized samples. The filter material has been replaced and the mechanical filters have been connected. The first stage of the filter has been replaced, the second stage of the filter and final purification filters Н-OH have been installed.

Results. The authors have demonstrated the possibility to use boilers with seasonal operating modes and measuring the electrical conductivity of cooled water and steam samples as a chemical control of water chemistry. It is found out that dosing the VTIAMIN KR-33 reagent with periodic dosing of the VTIAMIN D-8 reagent into the boiler water prevent the precipitation of hardness salts and other impurities coming with the return condensate. Analysis of the indicators of the water chemistry regime at the thermal power plant when dosing the VTIAMIN KR-33 reagent at two points has shown that the pH value of the feed water is in the range of 8,8–9,0 and the indicators of the water chemistry regime in terms of the content of iron, silicic acid and sodium are also within the norm limits. The composition of the reagents is selected. Flexibility of water chemistry management is ensured. It has been shown that the dosage of the amine-containing reagent VTIAMIN neutralizes the negative effects of aggressive gases (carbon dioxide and oxygen) due to their binding and the formation of a protective film of the magnetite-amine type on heating surfaces.

Conclusions. Introduction of the water chemical regime when the equipment is stopped as a reserve does not require additional preservation measures.

References in English: 

1. Guseva, O.V., Butakova, M.V. Rezul'taty vnedreniya kombinirovannogo vodno-khimicheskogo rezhima parovykh kotlov s ispol'zovaniem reagenta AMINAT TM PK-2 [Results of the implementation of a combined water-chemical regime of steam boilers using the reagent AMINAT TM PK-2]. Novoe v Rossiyskoy elektroenergetike, 2020, no. 4, pp. 12–20.

2. Petrova, T.I., Dyachenko, F.V., Orlov, K.A. Otechestvennye i mezhdunarodnye dokumenty po ispol'zovaniyu reagentov, soderzhashchikh plenkoobrazuyushchie aminy, dlya organizatsii vodno-khimicheskogo rezhima na TES [Domestic and international documents on the use of reagents containing film-forming amines for organizing the water chemical regime at thermal power plants]. Teploenergetika, 2018, no. 4, pp. 60–64.

3. Suslov, S.Yu., Kirilina, A.V., Sergeev, I.A., Zezyulya, T.V., Sokolova, E.A., Eremina, E.V., Timofeev, N.V. Kompleksnye reagenty na osnove aminov [Complex reagents based on amines]. Teploenergetika, 2017, no. 3, pp. 92–96.

4. Kirilina, A.V., Suslov, S.Yu., Nartya, E.F., Kozlovsky, V.V., Zidikhanova, A.A., Larin, A.B. Modernizatsiya vodno-khimicheskogo rezhima parovykh barabannykh kotlov na osnove reagenta VTIAMIN [Modernization of the water-chemical regime of steam drum boilers based on the reagent VTIAMIN]. Energetik, 2023, no. 3, pp. 9–17.

5. Suslov, S.Yu., Kirilina, A.V., Sergeev, I.A., Sokolova, E.A., Suslov, I.S., Suslov, P.S. Nekotorye osobennosti svoystv kompleksnykh reagentov na osnove aminov i vodno-khimicheskiy rezhim [Some features of the properties of complex reagents based on amines and the water-chemical regime]. Energetik, 2013, no. 2, pp. 28–35.

Key words in Russian: 
паровой котел, энерготехнологическое оборудование, аминосодержащий реагент, водно-химический режим
Key words in English: 
steam boiler, power technology equipment, amino-containing reagent, water-chemical regime
The DOI index: 
10.17588/2072-2672.2024.2.005-014
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